Amino Acids, Peptides and Proteins (SPR Amino Acids, by G. T. Young

By G. T. Young

Expert Periodical reviews offer systematic and particular evaluate insurance of growth within the significant parts of chemical study. Written through specialists of their professional fields the sequence creates a special carrier for the lively study chemist, offering standard serious in-depth money owed of growth specifically parts of chemistry.

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Additional info for Amino Acids, Peptides and Proteins (SPR Amino Acids, Peptides, and Proteins (RSC)) (vol. 4)

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1971,B27, 1517. llS P. S. Naganathan and K. , 1971,B27,2159. H. Hinazumi and T. , 1971, B27, 2152. 120 R. J. Jandacek and K. M. , 1971, B27, 841. lZ1 E. Bye, A. Mostad, and C. Rprmming, Actu Chem. , 1971, 25, 364. lea T. Matsuzaki and Y . , 1971, B27, 507. la3 A. Aubry, M. Marraud, J. Protas, and J. Neel, Compt. , 1971, 273, C, 959. la' V. Cody, W. L. Duax, and D. A. Norton, Chem. , 1971, 683. la6 P. Groth, Acta Chem. , 1971, 25, 118. 112 2 Amino-acids, Peptides, and Proteins 18 HO,C B. r. spectroscopy is now an indispensable tool for structural elucidation and has played a decisive role in the characterization of many of the new amino-acids described in Section 1 (see, for example, refs.

Unkeless and P. Goldman, Mol. , 1971,7, 293. K. F. Turchin, M. N. Preobrazhenskaya, Yu. N. Sheinker, and N. N. Suvorov, Zhur. org. , 1971, 7 , 1290. f61 4 Chemical Studies of Amino-acids A. lsa Although the first issue contained only a limited amount on amino-acids (assignment of configuration), the series offers a further source of information on amino-acid chemistry. Each year a great deal of research is published on the chemistry of amino-acids and their derivatives, much of it in relation to peptide synthesis, and this is presented elsewhere in this Report; the remainder is undertaken for a wide variety of reasons and it is therefore inevitable that this section is something of a miscellany.

Spectra obtained are essentially identical. r. studies on radicals produced by radiolysis support the generally established pathways for the reaction of amino-acids with OH radicals and hydrated e l e c t r ~ n s , l ~and ~ - in ~ ~the ~ aqueous alkaline solution of all the amino-acids investigated, radicals of the type (59) were 0 b ~ e r v e d . l ~ ~ Similar observations were made on the radicals produced with Ti3+-H202 at pH 9-12, and in this case the temperature-dependent proton hyperfine splitting from the amino-hydrogens was noted and interpreted in terms of lS9 lg4 lg6 le6 lsB 2oo T.

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